Basalt

Relative to most common igneous rocks, basalt compositions are rich in MgO and CaO and low in SiO2 and the alkali oxides, i.e., Na2O + K2O, consistent with the TAS classification. Basalt generally has a composition of 45–55 wt% SiO2, 2–6 wt% total alkalis, 0.5–2.0 wt% TiO2, 5–14 wt% FeO and 14 wt% or more Al2O3. Contents of CaO are commonly near 10 wt%, those of MgO commonly in the range 5 to 12 wt%. High-alumina basalts have aluminium contents of 17–19 wt% Al2O3; boninites have magnesium (MgO) contents of up to 15 percent. Rare feldspathoid-rich mafic rocks, akin to alkali basalts, may have Na2O + K2O contents of 12% or more. The abundances of the lanthanide or rare-earth elements (REE) can be a useful diagnostic tool to help explain the history of mineral crystallisation as the melt cooled. In particular, the relative abundance of europium compared to the other REE is often markedly higher or lower, and called the europium anomaly. It arises because Eu can substitute for Ca in plagioclase feldspar, unlike any of the other lanthanides, which tend to only form 3+ cations. Mid-ocean ridge basalts (MORB) and their intrusive equivalents, gabbros, are the characteristic igneous rocks formed at mid-ocean ridges. They are tholeiitic basalts particularly low in total alkalis and in incompatible trace elements, and they have relatively flat rare-earth element (REE) patterns normalized to mantle or chondrite values. In contrast, alkali basalts have normalized patterns highly enriched in the light REE, and with greater abundances of the REE and of other incompatible elements. Because MORB basalt is considered a key to understanding plate tectonics, its compositions have been much studied. Although MORB compositions are distinctive relative to average compositions of basalts erupted in other environments, they are not uniform. For instance, compositions change with position along the Mid-Atlantic Ridge, and the compositions also define different ranges in different ocean basins. Mid-ocean ridge basalts have been subdivided into varieties such as normal (NMORB) and those slightly more enriched in incompatible elements (EMORB). Isotope ratios of elements such as strontium, neodymium, lead, hafnium, and osmium in basalts have been much studied to learn about the evolution of the Earth's mantle. Isotopic ratios of noble gases, such as He/He, are also of great value: for instance, ratios for basalts range from 6 to 10 for mid-ocean ridge tholeiitic basalt (normalized to atmospheric values), but to 15–24 and more for ocean-island basalts thought to be derived from mantle plumes. Source rocks for the partial melts probably include both peridotite and pyroxenite (e.g., Sobolev et al., 2007).