Hübnerite
A variety of Wolframite Group

What is Hübnerite?
Hübnerite is a rare mineral that sometimes co-occurs with well-known gemstones such as tourmaline and topaz. Hübnerite’s color may range from dull yellow-brown to a deep and striking shade of brick red. The mineral is an ore of tungsten, an element with many commercial industrial uses (perhaps most famously, it is used to make light bulb filaments).
Optical Properties
- Refractive Index
- 2.17-2.32
- Birefringence
- 0.13
- Pleochroism
- Perceptible: yellow to green/red-orange, yellowish brown to greenish yellow/red-orange to red, green/brick-red to red
- Optical Character
- Biaxial positive
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Key Characteristics
Characteristics of Hübnerite
Color differences between members of the wolframite family are clear and marked. The color of hübnerite varies from yellowish brown to reddish brown. Crystal and crystalline masses of hübnerite show a variety of lusters from adamantine, submetallic to resinous luster. In thin splints, hübnerite can be either transparent or translucent. The streak is related to the color being a shade lighter. All the wolframite minerals exhibit perfect cleavage on {010}. On {100} and {102}, parting is less well-developed. Hübnerite exhibits brittle and uneven fracture. It is common for all members of the wolframite family to show simple contact twins on {100} or rarely interpenetrant twins on {001}. The hardness of hübnerite is between 4 and 4.5 and its specific gravity is between 7.12 and 7.18.
Formation of Hübnerite
Hübnerite is a rare member of the wolframite group. Hübnerite is usually found within pegmatites and high-temperature quartz veins. Hübnerite does not occur on its own, but is typically associated with other minerals such as cassiterite, scheelite, quartz, galena, arsenopyrite, native bismuth, pyrite, and sphalerite.
Composition of Hübnerite
Since hübnerite comes from a family with only two end members it would be easier to explain the composition of the wolframite family since there is not enough data on hübnerite itself. The primary formula of the wolframite series is (Fe,Mn)WO4. The predominance of either iron or manganese results in formation of one of two minerals, the compositional end-members FeWO4 (ferberite) and MnWO4 (hübnerite), respectively.. Hübnerite is rarer than ferberite because of the difficulty of substituting manganese for iron. There are also other analogues, such as MgWO4. These compounds are usually referred to as "wolframites" because they share the wolframite structure, but are not naturally occurring minerals, typically being produced for industrial applications, e.g., crystal scintillators.
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Quick Facts
Physical Properties
- Color
- Yellow-brown, reddish-brown, blackish brown, black, red rare
- Hardness (Mohs)
- 4 - 4.5
- Density
- 7.234 g/cm³
- Streak
- Greenish-grey, yellow to reddish-brown
- Luster
- Resinous, Metallic, Adamantine
- Crystal System
- Monoclinic
Chemical Properties
- Chemical Formula
- MnWO4
- Elements
- Mn, O, W
Also Known As

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