Leonite

A variety of Leonite Group

Leonite specimen - rock identification

What is Leonite?

Leonite is a hydrated double sulfate of magnesium and potassium. It has the formula K2SO4·MgSO4·4H2O. The mineral was named after Leo Strippelmann, who was director of the salt works at Westeregeln in Germany. The mineral is part of the blodite group of hydrated double sulfate minerals.

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North ZoneCentral RidgeSouth Basin

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Key Characteristics

Characteristics of Leonite

Leonite has a bitter taste. When leonite is analyzed for elements, it is usually contaminated with sodium and chloride ions, as it commonly occurs with sodium chloride.

Formation of Leonite

Starting in 1897, Jacobus Henricus van 't Hoff investigated how different salts were formed as sea water evaporated in different conditions. His purpose was to discover how salt deposits are formed. His research formed the basis for the studies of the conditions in which leonite is formed. Leonite can form when a water solution of potassium sulfate and magnesium sulfate is concentrated between the temperature range of 320–350 K (47–77 °C). Above this temperature range, langbeinite (K2Mg2(SO4)3) is formed. Below 320 K (47 °C), picromerite (K2Mg(SO4)2·6H2O) crystallises. For solutions with more than 90% proportion MgSO4, hexahydrite (MgSO4·6H2O) crystallises preferentially, and below 60%, arcanite (K2SO4) forms. In mixtures of potassium chloride, potassium sulfate, magnesium chloride and magnesium sulfate at 35 °C in water, leonite can crystallise out in a certain composition range. The plot of the system forms boundaries of leonite with potassium chloride, potassium sulfate, and picromerite. As magnesium is enriched, a quadruple point with kainite exists. In salt (NaCl) saturated brine, leonite can be deposited from magnesium and potassium sulfate mixtures as low as 25 °C. The 25 °C isotherm of the system has leonite surrounded by sylvine, picromerite, astrakanite, epsomite, and kainite. Sodium chloride saturated brines are formed by seawater evaporation, though seawater does not contain enough potassium to deposite leonite this way. Leonite is precipitated in series solar ponds at the Great Salt Lake. When picromerite is heated to between 85 and 128 °C, it gives off steam to give leonite: K2Mg(SO4)2·6H2O(s) → K2Mg(SO4)2·4H2O(s) + 2H2O(g).

Composition of Leonite

In the mineral family of leonite, the lattice contains sulfate tetrahedrons, a divalent element in an octahedral position surrounded by oxygen, and water and univalent metal (potassium) linking these other components together. One sulfate group is disordered at room temperature. The disordered sulfate becomes fixed in position as temperature is lowered. The crystal form also changes at lower temperatures, so two other crystalline forms of leonite exist at lower temperatures. The divalent metal cation (magnesium) is embedded in oxygen octahedra, four from water around the equator, and two from sulfate ions at the opposite poles. In the crystal there are two different octahedral environments. Each of these octahedra are joined together by potassium ions and hydrogen bonds.

More Images

Leonite specimen 2
© Robert M. Lavinsky
Leonite specimen 3
© Robert M. Lavinsky

Quick Facts

Physical Properties

Color
Colourless, pale yellow; colourless (transmitted light).
Hardness (Mohs)
2.5 - 3
Density
2.201 g/cm³

Chemical Properties

Chemical Formula
K2Mg(SO4)2 · 4H2O
Elements
H, K, Mg, O, S

Also Known As

LeoniteMagnesium leonite
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