Borax
A variety of Minerals
What is Borax?
Borax, also known as sodium borate, sodium tetraborate, or disodium tetraborate, is a compound with formula Na2H4B4O9•nH2O or, more precisely, [Na•(H2O)m]2 [B4O5(OH)4]. The formula is often improperly written as Na2B4O7•(n+2)H2O, reflecting an older incorrect understanding of the anion's molecular structure. The name may refer to any of a number of closely related boron-containing mineral or chemical compounds that differ in their water of crystallization content. The most commonly encountered one is the octahydrate Na2H4B4O9•8H2O or [Na(H2O)4]2 [B4O5(OH)4] (or Na2B4O7•10H2O, the "decahydrate", in the older notation). It is a colorless crystalline solid that dissolves in water. Borax is a component of many detergents, cosmetics, and enamel glazes. It is used to make buffer solutions in biochemistry, as a fire retardant, as an anti-fungal compound, in the manufacture of fiberglass, as a flux in metallurgy, neutron-capture shields for radioactive sources, a texturing agent in cooking, as a cross-linking agent in slime, as an alkali in photographic developers, as a precursor for other boron compounds, and is useful as an insecticide (similarly to boric acid). In artisanal gold mining, borax is sometimes used as part of a process (as a flux) meant to eliminate the need for toxic mercury in the gold extraction process, although it cannot directly replace mercury. Borax was reportedly used by gold miners in parts of the Philippines in the 1900s. Borax was first discovered in dry lake beds in Tibet and was imported via the Silk Road to the Arabian Peninsula in the 8th century AD. Borax first came into common use in the late 19th century when Francis Marion Smith's Pacific Coast Borax Company began to market and popularize a large variety of applications under the 20 Mule Team Borax trademark, named for the method by which borax was originally hauled out of the California and Nevada deserts.
Etymology & Origins
The English word borax is Latinized: the Middle English form was boras, from Old French boras, bourras. That may have been from medieval Latin baurach (another English spelling), borac(-/um/em), borax, along with Spanish borrax (> borraj) and Italian borrace, in the 9th century. Another name for borax is tincal, from Sanskrit. The word tincal /ˈtɪŋkəl/ "tinkle", or tincar /ˈtɪŋkər/ "tinker", refers to crude borax, before it is purified, as mined from lake deposits in Tibet, Persia, and other parts of Asia. The word was adopted in the 17th century from Malay tingkal and from Urdu/Persian/Arabic تنکار tinkār/tankār; thus the two forms in English. These all appear to be related to the Sanskrit टांकण ṭānkaṇa.
Uses & Applications
Medicinal Anti-fungal foot soak Treatment for thrush in horses' hoofs Is found in some commercial vitamin supplements Other Ingredient in enamel glazes Component of glass, pottery, and ceramics Used as an additive in ceramic slips and glazes to improve fit on wet, greenware, and bisque Fire retardant Anti-fungal compound for cellulose insulation Moth proofing 10% solution for wool Pulverized for the prevention of stubborn pests (e.g. German cockroaches) in closets, pipe and cable inlets, wall panelling gaps, and inaccessible locations where ordinary pesticides are undesirable Precursor for sodium perborate monohydrate that is used in detergents, as well as for boric acid and other borates Tackifier ingredient in casein, starch and dextrin based adhesives Precursor for boric acid, a tackifier ingredient in polyvinyl acetate, polyvinyl alcohol based adhesives To make indelible ink for dip pens by dissolving shellac into heated borax Curing agent for snake skins Curing agent for salmon eggs, for use in sport fishing for salmon Swimming pool buffering agent to control pH Neutron absorber, used in nuclear reactors and spent fuel pools to control reactivity and to shut down a nuclear chain reaction As a micronutrient fertilizer to correct boron-deficient soils. Preservative in taxidermy To color fires with a green tint Was traditionally used to coat dry-cured meats such as hams to improve the appearance and discourage flies. For stopping car radiator and engine block leaks Used by blacksmiths in forge welding Used as a woodworm treatment (diluted in water) Used as an insecticide in some ant baits. It kills ants slowly, allowing the ants time to bring the poison back to the colony, killing the queen and eventually the entire colony. Deodorizer for carpets, sprinkle on and leave for a while and vacuum it up
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Key Characteristics
Composition of Borax
The term borax is often used for a number of closely related minerals or chemical compounds that differ in their crystal water content: anhydrous sodium tetraborate, Na2B4O7 sodium tetraborate pentahydrate, Na2B4O7·5H2O sodium tetraborate decahydrate, Na2B4O7·10H2O or equivalently the octahydrate, Na2B4O5(OH)4·8H2O From the chemical perspective, borax contains the [B4O5(OH)4] ion. In this structure, there are two four-coordinate boron centers and two three-coordinate boron centers.
Health & Safety Information
- ⚠️Borax, sodium tetraborate decahydrate, according to one study, is not acutely toxic. Its LD50 (median lethal dose) score is tested at 4.55-6.08 g/kg in rats as determined by US EPA (1969), later in 1972 found to be 4.5 g/kg, meaning that a significant dose of the chemical is needed to cause severe symptoms or death. The lethal dose is not necessarily the same for humans. On pesticide information websites it is listed as a non-lethal compound and of no hazardous concerns. Borax has been in use as an insecticide in the United States with various restrictions since 1946. All restrictions were removed in February 1986 due to the low toxicity of borax, as reported in two EPA documents relating to boric acid and borax. EPA has determined that, because they are of low toxicity and occur naturally, boric acid and its sodium salts should be exempted from the requirement of a tolerance (maximum residue limit) for all raw agricultural commodities. Although it cited inconclusive data, a re-evaluation in 2006 by the EPA still found that "There were no signs of toxicity observed during the study and no evidence of cytotoxicity to the target organ." In the reevaluation, a study of toxicity due to overexposure was checked and the findings were that "The residential handler inhalation risks due to boric acid and its sodium salts as active ingredients are not a risk concern and do not exceed the level of concern..." but that there could be some risk of irritation to children inhaling it if used as a powder for cleaning rugs. Sodium tetraborate decahydrate has no known hazard issues. Overexposure to borax dust can cause respiratory irritation, while no skin irritation is known to exist due to external borax exposure. Ingestion may cause gastrointestinal distress including nausea, persistent vomiting, abdominal pain, and diarrhea. Effects on the vascular system and human brain include headaches and lethargy, but are less frequent. In severe cases, a "beefy" red rash affecting the palms, soles, buttocks and scrotum has occurred. Due to concerns about the toxicity of borax which was withdrawn as a cleaning and laundry product, sodium sesquicarbonate is sold in the European Union (EU) as "Borax substitute". It is also known as one of the E number food additives E500. During the 1951 Indianapolis 500, race winner Lee Wallard coated his racing suit with a fire retardant mixture of borax crystals and water. He suffered serious chafing, and required treatment at the infield hospital after the victory lane celebration.
Quick Facts
Physical Properties
- Color
- Colourless, grey, white, yellowish, seldom bluish or greenish; colourless in transmitted light.
- Hardness (Mohs)
- 2 - 2.5
- Density
- 1.7 g/cm³
- Streak
- White
Chemical Properties
- Chemical Formula
- Na2(B4O5)(OH)4 · 8H2O
- Elements
- B, H, Na, O
Also Known As

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