Pararealgar

A variety of Minerals

What is Pararealgar?

Pararealgar is an arsenic sulfide mineral with the chemical formula As4S4 also represented as AsS. It forms gradually from realgar under exposure to light. Its name derives from the fact that its elemental composition is identical to realgar, As4S4. It is soft with a Mohs hardness of 1 - 1.5, is yellow orange in colour, and its monoclinic prismatic crystals are very brittle, easily crumbling to powder. It is one of the sulfides of arsenic and is one of two isomers of As4S4. It forms upon exposure of the symmetrical isomer to light. Its name derives from the fact that its elemental composition is identical to realgar, As4S4.

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North ZoneCentral RidgeSouth Basin

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Key Characteristics

Formation of Pararealgar

As stated above, pararealgar is an alteration product of realgar resulting from exposure to light. The process of alteration is dependent on the wavelength of light, with alteration only occurring at wavelengths longer than approximately 500 nm, in the visible light spectrum. In realgar's crystal structure, each arsenic atom is bonded to two sulphur atoms and one other arsenic atom. The As-As bonds are 30% weaker than the As-S bonds and certain wavelengths of lights interact with the crystal structure of realgar, breaking the weaker bonds between arsenic atoms. The free As formed as a result of this process destabilises the realgar structure, causing the realgar to become powdery pararealgar without changing overall chemical composition.

Composition of Pararealgar

Both isomers of As4S4 are molecular, in contrast to the other main sulfide of arsenic, orpiment (As2S3), which is polymeric. In pararealgar, there are three kinds of As centres (and three kinds of S centres). The molecule has Cs symmetry. In realgar, the four As (and four S) centres are equivalent and the molecule has D2d symmetry. An analogous pair of isomers is also recognized for the corresponding phosphorus sulfides P4S4.

Quick Facts

Physical Properties

Color
Light yellow to orange-brown
Hardness (Mohs)
1 - 1.5
Streak
Light yellow

Chemical Properties

Chemical Formula
As4S4
Elements
As, S
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