Sulphur

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What is Sulphur?

Sulfur (in traditional lay Commonwealth English: sulphur) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most common element by mass in the universe, and the fifth most common on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum. The greatest commercial use of the element is the production of sulfuric acid for sulfate and phosphate fertilizers, and other chemical processes. The element sulfur is used in matches, insecticides, and fungicides. Many sulfur compounds are odoriferous, and the smells of odorized natural gas, skunk scent, grapefruit, and garlic are due to organosulfur compounds. Hydrogen sulfide gives the characteristic odor to rotting eggs and other biological processes. Sulfur is an essential element for all life, but almost always in the form of organosulfur compounds or metal sulfides. Three amino acids (cysteine, cystine, and methionine) and two vitamins (biotin and thiamine) are organosulfur compounds. Many cofactors also contain sulfur, including glutathione, thioredoxin, and iron–sulfur proteins. Disulfides, S–S bonds, confer mechanical strength and insolubility of the protein keratin, found in outer skin, hair, and feathers. Sulfur is one of the core chemical elements needed for biochemical functioning and is an elemental macronutrient for all living organisms.

Uses & Applications

Elemental sulfur is used mainly as a precursor to other chemicals. Approximately 85% (1989) is converted to sulfuric acid (H2SO4). Sulfur is increasingly used as a component of fertilizers. The most important form of sulfur for fertilizer is the mineral calcium sulfate. Organosulfur compounds are used in pharmaceuticals, dyestuffs, and agrochemicals.

Optical Properties

Refractive Index
1.958-2.245
Birefringence
0.291
Optical Character
Biaxial positive

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Sulphur Localities Map

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North ZoneCentral RidgeSouth Basin

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The Meaning

Sulphur was known since ancient times and was considered one of the three basic alchemic materials. In the Holy Bible, sulphur is called the "brimstone", which means "firestone" and it's associated with Hell. Ancient Chinese believed that sulphur had healing properties.

Key Characteristics

Characteristics of Sulphur

Sulfur forms several polyatomic molecules. The best-known allotrope is octasulfur, cyclo-S8. The point group of cyclo-S8 is D4d and its dipole moment is 0 D. Octasulfur is a soft, bright-yellow solid that is odorless, but impure samples have an odor similar to that of matches. It melts at 115.21 °C (239.38 °F), boils at 444.6 °C (832.3 °F) and sublimes easily. At 95.2 °C (203.4 °F), below its melting temperature, cyclo-octasulfur changes from α-octasulfur to the β-polymorph. The structure of the S8 ring is virtually unchanged by this phase change, which affects the intermolecular interactions. Between its melting and boiling temperatures, octasulfur changes its allotrope again, turning from β-octasulfur to γ-sulfur, again accompanied by a lower density but increased viscosity due to the formation of polymers. At higher temperatures, the viscosity decreases as depolymerization occurs. Molten sulfur assumes a dark red color above 200 °C (392 °F). The density of sulfur is about 2 g/cm, depending on the allotrope; all of the stable allotropes are excellent electrical insulators.

Quick Facts

Physical Properties

Color
Yellow, sulphur-yellow, brownish or greenish yellow, orange, white
Hardness (Mohs)
1.5 - 2.5
Density
2.076 g/cm³
Streak
Colourless

Chemical Properties

Chemical Formula
S8
Elements
S

Also Known As

SulphurAlpha-sulphurBrimstoneNative SulfurSulfur-alpha
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