Coal

A variety of Sedimentary

Common

What is Coal?

One of the most famous and widely-used substances in the world, coal is a dark-colored rock that is rich in carbon. It was formed from decaying plant and animal material, compressed under the earth over millions of years. Coal provided the heat and energy needed to spur the industrial era in the 1800s, though it is thought to have been used for household heating in China as far back as 3000 BC.

Etymology & Origins

The word originally took the form col in Old English, from Proto-Germanic *kula(n), which in turn is hypothesized to come from the Proto-Indo-European root *g(e)u-lo- "live coal". Germanic cognates include the Old Frisian kole, Middle Dutch cole, Dutch kool, Old High German chol, German Kohle and Old Norse kol, and the Irish word gual is also a cognate via the Indo-European root.

Uses & Applications

Coal has been used for centuries for heating and fuel, with applications ranging from heating a kitchen stove to fueling a steam engine. Today it is commonly used to generate electricity, making this rock one of the most impactful fossil fuels known today.

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Geochemistry

The composition of coal is reported either as a proximate analysis (moisture, volatile matter, fixed carbon, and ash) or an ultimate analysis (ash, carbon, hydrogen, nitrogen, oxygen, and sulfur). The "volatile matter" does not exist by itself (except for some adsorbed methane) but designates the volatile compounds that are produced and driven off by heating the coal. A typical bituminous coal may have an ultimate analysis on a dry, ash-free basis of 84.4% carbon, 5.4% hydrogen, 6.7% oxygen, 1.7% nitrogen, and 1.8% sulfur, on a weight basis.

Key Characteristics

Rock Types of Coal

As geological processes apply pressure to dead biotic material over time, under suitable conditions, its metamorphic grade or rank increases successively into: Peat, a precursor of coal Lignite, or brown coal, the lowest rank of coal, most harmful to health, used almost exclusively as fuel for electric power generation Sub-bituminous coal, whose properties range between those of lignite and those of bituminous coal, is used primarily as fuel for steam-electric power generation. Bituminous coal, a dense sedimentary rock, usually black, but sometimes dark brown, often with well-defined bands of bright and dull material. It is used primarily as fuel in steam-electric power generation and to make coke. Known as steam coal in the UK, and historically used to raise steam in steam locomotives and ships Anthracite, the highest rank of coal, is a harder, glossy black coal used primarily for residential and commercial space heating. Graphite is difficult to ignite and not commonly used as fuel; it is most used in pencils, or powdered for lubrication.

Characteristics of Coal

Emission intensity is the greenhouse gas emitted over the life of a generator per unit of electricity generated. Of the currently widely used methods of generating electricity the emission intensity of coal and oil is high, as they emit around 1000g of CO2eq for each kWh generated; natural gas is medium emission intensity at around 500g CO2eq per kWh; and all other methods are typically low emission intensity of under 100g per kWh. The emission intensity of coal varies with type and generator technology and exceeds 1200g per kWh in some countries. The energy density of coal, that is its heating value, is roughly 24 megajoules per kilogram (approximately 6.7 kilowatt-hours per kg). For a coal power plant with a 40% efficiency, it takes an estimated 325 kg (717 lb) of coal to power a 100 W lightbulb for one year. 27.6% of world energy was supplied by coal in 2017 and Asia used almost three quarters of it.

Formation of Coal

Coal is mostly carbon with variable amounts of other elements; chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands—called coal forests—that covered much of the Earth's tropical land areas during the late Carboniferous (Pennsylvanian) and Permian times.

Composition of Coal

Coal is composed of macerals, minerals and water. Fossils and amber may be found in coal.

Health & Safety Information

  • ⚠️"The use of coal as fuel causes ill health and deaths. Mining and processing of coal causes air and water pollution. Coal-powered plants emit nitrogen oxides, sulfur dioxide, particulate pollution and heavy metals, which adversely affect human health. Coal bed methane extraction is important to avoid mining accidents. The deadly London smog was caused primarily by the heavy use of coal. Globally coal is estimated to cause 800,000 premature deaths every year, mostly in India and China. Burning coal is a major emitter of sulfur dioxide, which creates PM2.5 particulates, the most dangerous form of air pollution. Coal smokestack emissions cause asthma, strokes, reduced intelligence, artery blockages, heart attacks, congestive heart failure, cardiac arrhythmias, mercury poisoning, arterial occlusion, and lung cancer. Annual health costs in Europe from use of coal to generate electricity are estimated at up to €43 billion. In China, improvements to air quality and human health would increase with more stringent climate policies, mainly because the country's energy is so heavily reliant on coal. And there would be a net economic benefit. A 2017 study in the Economic Journal found that for Britain during the period 1851–1860, ""a one standard deviation increase in coal use raised infant mortality by 6–8% and that industrial coal use explains roughly one-third of the urban mortality penalty observed during this period."" Breathing in coal dust causes coalworker's pneumoconiosis which is known colloquially as ""black lung"", so-called because the coal dust literally turns the lungs black from their usual pink color. In the United States alone, it is estimated that 1,500 former employees of the coal industry die every year from the effects of breathing in coal mine dust. Huge amounts of coal ash and other waste is produced annually. Use of coal generates hundreds of millions of tons of ash and other waste products every year. These include fly ash, bottom ash, and flue-gas desulfurization sludge, that contain mercury, uranium, thorium, arsenic, and other heavy metals, along with non-metals such as selenium. Around 10% of coal is ash: coal ash is hazardous and toxic to human beings and some other living things. Coal ash contains the radioactive elements uranium and thorium. Coal ash and other solid combustion byproducts are stored locally and escape in various ways that expose those living near coal plants to radiation and environmental toxics. Coal mining and coal fueling of power stations and industrial processes can cause major environmental damage. Water systems are affected by coal mining. For example, mining affects groundwater and water table levels and acidity. Spills of fly ash, such as the Kingston Fossil Plant coal fly ash slurry spill, can also contaminate land and waterways, and destroy homes. Power stations that burn coal also consume large quantities of water. This can affect the flows of rivers, and has consequential impacts on other land uses. In areas of water scarcity, such as the Thar Desert in Pakistan, coal mining and coal power plants would use significant quantities of water. One of the earliest known impacts of coal on the water cycle was acid rain. Approximately 75 Tg/S per year of sulfur dioxide (SO2) is released from burning coal. After release, the sulfur dioxide is oxidized to gaseous H2SO2 which scatters solar radiation, hence its increase in the atmosphere exerts a cooling effect on climate. This beneficially masks some of the warming caused by increased greenhouse gases. However, the sulfur is precipitated out of the atmosphere as acid rain in a matter of weeks, whereas carbon dioxide remains in the atmosphere for hundreds of years. Release of SO2 also contributes to the widespread acidification of ecosystems. Disused coal mines can also cause issues. Subsidence can occur above tunnels, causing damage to infrastructure or cropland. Coal mining can also cause long lasting fires, and it has been estimated that thousands of coal seam fires are burning at any given time. For example, Brennender Berg has been burning since 1668 and is still burning in the 21st century. The production of coke from coal produces ammonia, coal tar, and gaseous compounds as by-products which if discharged to land, air or waterways can pollute the environment. The Whyalla steelworks is one example of a coke producing facility where liquid ammonia is discharged to the marine environment."

Quick Facts

Physical Properties

Color
Black, brown, dark brown, grey, light to dark grey
Density
1.1 - 1.4 g/cm³
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