Ajoite

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Ajoite specimen - rock identification

What is Ajoite?

Ajoite is a hydrated sodium potassium copper aluminium silicate hydroxide mineral. Ajoite has the chemical formula (Na,K)Cu7AlSi9O24(OH)6·3H2O, and minor Mn, Fe and Ca are usually also present in the structure. Ajoite is used as a minor ore of copper.

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Key Characteristics

Characteristics of Ajoite

The cleavage is perfect parallel to the plane containing the a and c axes, and the hardness is 3.5, between that of calcite and fluorite. It is a little denser than quartz, with specific gravity 2.96. Ajoite is readily decomposed by hydrochloric acid, HCl, and by nitric acid, HNO3, but it does not react with ammonium hydroxide, NH4OH. It has been reported as having barely detectable radioactivity.

Formation of Ajoite

Ajoite is named after its type locality, the New Cornelia Mine in the Ajo District of Pima County, Arizona. Type material is conserved at the National Museum of Natural History, Washington DC, USA, reference number 113220. Other localities include Wickenburg and Maricopa County in Arizona, within the United States, and the Messina (Musina) District in South Africa. Quartz specimens from the defunct Messina Mines on the border between Zimbabwe and South Africa are well known for their inclusions of blue copper silicate minerals such as shattuckite, papagoite and ajoite, but ajoite from American localities does not occur like this.

Composition of Ajoite

The 1981 investigations of ajoite were done on a sample from the New Cornelia Mine, Ajo, with tiny crystals averaging 0.01×0.1×0.4 mm. The mineral was shown to belong to the triclinic system, but it was not clear whether the crystal class was 1 or 1. The triclinic class 1 has the lowest possible symmetry with no symmetry elements at all, and 1 has just a centre of symmetry, but no axes of symmetry or mirror planes. The space group is either P1 or P1. The unit cell parameters are: a = 13.637 Å, b = 14.507 Å, c = 13.620 Å, α = 107.16°, β = 105.45° and γ = 110.57°. Ajoite occurs as sprays of bladed prismatic crystals, commonly fibrous, elongated along the c crystal axis and flattened sideways. The dominant form is {010}, parallel to the plane containing the a and c axes. The forms {110}, cutting both the a and b axes, and {100}, parallel to the plane containing the b and c axes, are much less prominent but are always present. The termination on c may be either {001} or {203} or both. Ajoite is frequently found as inclusions in quartz, much sought after by mineral collectors.

More Images

Ajoite specimen 2
© Robert M. Lavinsky

Quick Facts

Physical Properties

Color
Bluish green
Density
2.951 g/cm³
Streak
Greenish white

Chemical Properties

Chemical Formula
(K,Na)Cu7AlSi9O24(OH)6 · 3H2O
Elements
Al, Cu, H, K, O, Si
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