Alforsite

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Alforsite specimen - rock identification

What is Alforsite?

Alforsite is a barium phosphate chloride mineral with formula: Ba5(PO4)3Cl. It was discovered in 1981, and named to honor geologist John T. Alfors (1930–2005) of the California Geological Survey for his work in the area where it was discovered. Alforsite is a hexagonal colorless crystal in the chemical class phosphates and the group apatite. It is found in certain parts of central California, primarily Fresno, Mariposa, and Tulare Counties. It has also been found in Baja California, Mexico. Alforsite is a constituent of the apatite group of minerals. It crystallizes in the hexagonal crystal system with a point group of 6/m and space group P63/m. It occurs as colorless grains that are hard to distinguish from fluoroapatite, as they both display low birefringence and high relief.

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Key Characteristics

Characteristics of Alforsite

Alforsite occurs as colorless, minuscule subhedral grains with a diameter less than 0.05 mm. However, on rare occasions, it can crystallize to a diameter up to 0.2 mm. Minerals that belong to different groups, such as silicates, and sulfates exhibit the structural typology of apatite. This can pose problems and confusion because alforsite bears an almost exact resemblance to other barium silicates, which exemplifies its group Greek name, apatao, meaning, “I am misleading”. The only way to differentiate alforsite from other barium minerals is through microchemical analysis (Walstrom and Leising, 2005). This misleading mineral emulates the physical and structural features of apatite and is analogously similar to chlorapatite, providing alfrosite with the alternate name, barium chlorapatite. Alforsite has a low birefringence and a high relief resembling fluorapatite in thin-section. A reddish-violet cathodoluminescence appears on thin-section showing major levels of chlorine, phosphorus, and barium. Alforsite can be recognized by electron microprobe analysis or by intense violet fluorescence in the 10-15 kV electron beam of a luminoscope

Composition of Alforsite

Alforsite's ideal chemical formula is Ba5(PO3)4Cl. Chemical analysis of the composition of alfrosite was demonstrated by the use of an Ortex current digitizer and an electron microbe. Synthetic barium chlorapatite, strontianite, and fluorapatite were used as standards for the elements they contain. The chemical analysis revealed that traces of Mn, S, Si, and Pb were present and provided computational formulas of (Ba4.68Sr0.19Ca0.13)(P2.98Si0.01)O11.96(Cl0.99F0.05) and (Ba4.05Ca0.75Sr0.24Pb0.03)(P2.94Si0.01)O11.93(Cl0.93F0.14).

Quick Facts

Physical Properties

Color
Colorless
Hardness (Mohs)
5
Density
4.8 g/cm³
Streak
White

Chemical Properties

Chemical Formula
Ba5(PO4)3Cl
Elements
Ba, Cl, O, P
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