Arthurite

A variety of Minerals

Arthurite specimen - rock identification

What is Arthurite?

Arthurite is a mineral composed of divalent copper and iron ions in combination with trivalent arsenate, phosphate and sulfate ions with hydrogen and oxygen. Initially discovered by Sir Arthur Russell in 1954 at Hingston Down Consols mine in Calstock, Cornwall, England, arthurite is formed as a resultant mineral in the oxidation region of some copper deposits by the variation of enargite or arsenopyrite. The chemical formula of Arthurite is CuFe2(AsO4,PO4,SO4)2(O,OH)2•4H2O. Arthurite is named after Arthur W. G. Kingsbury (1906–1968), a British mineralogist, and Sir Arthur Russell (1878–1964), a collector of minerals.

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North ZoneCentral RidgeSouth Basin

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Key Characteristics

Characteristics of Arthurite

Table 3. General and Physical Properties of arthurite

Composition of Arthurite

The theoretical chemical formula of Arthurite was originally determined to be Cu2Fe4(AsO4)3(O,OH)7•6H2O. The breakdown of the composition of arthurite in weight percent oxides is given in Table 1. Table 1. Chemical composition of Arthurite in weight percent oxides Arthurite crystallizes from an aqueous solution with whichever applicable anions are accessible in the solution. These available anions may be carbonate, arsenate, sulphate and phosphate. Some other minerals belonging to the arthurite group are cobaltarthurite, CoFe2(AsO4)2(OH)2•4H2O, whitmoreite FeFe2(PO4)2(OH)2•4H2O, ojuelaite, ZnFe2(AsO4)2(OH)2•4H2O, earlshannonite, (Mn,Fe)Fe2(PO4)2(OH)2•4H2O and bendadaite, FeFe2(AsO4)2(OH)2•4H2O. The optimal compositions of the members of the arthurite group can be represented by AFe2(XO4)2(OH)2•4H2O and are summarized in Table 2. Table 2. Compositional breakdown of the arthurite group members

Quick Facts

Physical Properties

Color
Apple-green, emerald-green, pale olive-green.
Hardness (Mohs)
3 - 4
Streak
(not reported)

Chemical Properties

Chemical Formula
CuFe3+2(AsO4)2(OH)2 · 4H2O
Elements
As, Cu, Fe, H, O
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