Barytocalcite

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Barytocalcite specimen - rock identification

What is Barytocalcite?

Barytocalcite is an anhydrous barium calcium carbonate mineral with the chemical formula BaCa(CO3)2. It is trimorphous with alstonite and paralstonite, that is to say the three minerals have the same formula but different structures. Baryte and quartz pseudomorphs after barytocalcite have been observed. Barytocalcite crystallizes in the monoclinic crystal system, typically as massive to druzy accumulations of transparent white to yellow to grey aggregates of slender prismatic crystals. It has a Mohs hardness of 4 and a specific gravity of 3.64 to 3.71. It was first described in 1824 for an occurrence in the Blagill Mine in North Pennines, Cumbria (Cumberland), England, and named for its composition.

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Key Characteristics

Characteristics of Barytocalcite

Barytocalcite has at least one perfect and one imperfect cleavage. It is a brittle mineral, and breaks with an uneven to conchoidal fracture. It is quite soft, with a hardness 4, the same as that of fluorite. Calcite CaCO3 and dolomite CaMg(CO3)2 are carbonates where calcium Ca and magnesium Mg replace the barium in the formula for barytocalcite, BaCa(CO3)2. These two minerals are even softer than barytocalcite, and much less dense. Barytocalcite has specific gravity 3.7. This is higher than that of calcite (2.7) or dolomite (2.85) because the barium atom is very heavy, with atomic mass 137, which is much more than magnesium at 24 and calcium at 40. Barytocalcite is soluble in dilute hydrochloric acid HCl and it is not radioactive.

Appearance of Barytocalcite

Barytocalcite often forms oriented growths on baryte, and calcite, witherite and baryte can be epitaxial on barytocalcite. Crystals are normally short to long prismatic and striated. They are transparent to translucent, colourless, white, greyish, greenish or yellowish with a white streak and a vitreous to resinous lustre.

Composition of Barytocalcite

The mineral crystallises in the monoclinic crystal system. Most sources put it in the prismatic class 2/m, with space group P21/m, but Webmin puts it in the sphenoidal class 2 with space group P21. The structure is similar to that of dolomite, but with two crystallographically different CO3 groups. The cation layers are stacked in an ABCABC... stacking pattern, repeating every 3 layers. The Ca ion is coordinated to 7 oxygens.

Quick Facts

Physical Properties

Color
Colourless, white, greyish, greenish, light yellow
Hardness (Mohs)
4
Density
3.65 g/cm³
Streak
White

Chemical Properties

Chemical Formula
BaCa(CO3)2
Elements
Ba, C, Ca, O
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