Carlosruizite

A variety of Minerals

What is Carlosruizite?

Carlosruizite is a sulfate or selenate – iodate mineral with chemical formula: K6(Na,K)4Na6Mg10(SeO4)12(IO3)12·12H2O. It has a low density (specific gravity of 3.36), colorless to pale yellow, transparent mineral which crystallizes in the trigonal crystal system. It forms a series with fuenzalidaite. It was first discovered in 1994 in the locality of Zapiga, Tarapacá Region of Chile. Its name came from Carlos Ruiz Fuller (1916–1997), founder of the Institute of Geological Investigations. It is found in samples of iquiqueite leached from caliche amarillo (yellow nitrate ore).

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North ZoneCentral RidgeSouth Basin

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Key Characteristics

Characteristics of Carlosruizite

Carlosruizite occurs as thin, colorless to pale yellow, transparent, euhedral, platy crystals with hexagonal outline, generally <200 μm in diameter and 20 μm thick. The crystals have a pseudorhombohedral habit, flattened on {0001} with beveled edges {1012}. They are slowly soluble in H2O. Surfaces of some crystals show abundant round or elongate cavities, which probably were formerly filled with saline fluids. The crystals are brittle and break easily into multiple fragments. Hardness is on the order of 2-3. The luster is vitreous.

Composition of Carlosruizite

Carlosruizite and fuenzalidate are members of a solid solution series K6(Na,K)4Na6Mg10(XO4)12(IO3)12·12H2O, for which the end-members have X = Se for the former and X = S for the latter. With the exception of selenium, the components of these minerals are widespread constituents of the Chilean nitrate ores. Se was not known to occur in these ores until it was discovered as a major component in carlosruizite by X-ray spectroscopy in the scanning electron microscope (SEM). Subsequent analyses of several specimens of nitrate ore from scattered localities in the Chilean nitrate fields showed them all to contain Se in amounts ranging from a few parts per million to nearly 50 ppm.

Quick Facts

Physical Properties

Color
Colourless to pale yellow.
Hardness (Mohs)
2.5 - 3
Density
3.4 g/cm³

Chemical Properties

Chemical Formula
K6(Na,K)4Na6Mg10(SeO4)12(IO3)12 · 12H2O
Elements
H, I, K, Mg, Na, O, Se
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