Coffinite

A variety of Minerals

Coffinite specimen - rock identification

What is Coffinite?

Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x. It occurs as black incrustations, dark to pale-brown in thin section. It has a grayish-black streak. It has a brittle to conchoidal fracture. The hardness of coffinite is between 5 and 6. It was first described in 1954 for an occurrence at the La Sal No. 2 Mine, Beaver Mesa, Mesa County, Colorado, US, and named for American geologist Reuben Clare Coffin (1886–1972). It has widespread global occurrence in Colorado Plateau-type uranium ore deposits of uranium and vanadium. It replaces organic matter in sandstone and in hydrothermal vein type deposits. It occurs in association with uraninite, thorite, pyrite, marcasite, roscoelite, clay minerals and amorphous organic matter.

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North ZoneCentral RidgeSouth Basin

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Key Characteristics

Characteristics of Coffinite

Initial examination of coffinite by Stieff et al. described the mineral as black in color with an adamantine luster, indistinguishable from uraninite (UO2). Additionally, the discoverers reported that although no cleavage is seen in coffinite, it does exhibit subconchoidal fracturing and is very fine grained. Initial samples showed a brittle texture and a hardness between 5 and 6, with a specific gravity of 5.1. Later samples from Woodrow Mine in New Mexico collected by Moench showed fibrous internal structure and exceptional crystallization. A polished thin section of coffinite has a brown color and shows anisotropic transmission of light. Optical analysis yielded a refractive index of about 1.74.

Composition of Coffinite

Coffinite's chemical formula is U(SiO4)1−x(OH)4x. X-ray powder patterns from samples of coffinite allowed geologists to classify it as a new mineral in 1955. A comparison to the x-ray powder pattern of zircon (ZrSiO4) and thorite (ThSiO4) was the basis for this classification. Preliminary chemical analysis indicated that the uranous silicate exhibited hydroxyl substitution. The results of Sherwood's preliminary chemical analysis were based on samples from three locations. Hydroxyl bonds and silicon-oxygen bonds also proved to exist after infrared absorption spectral analyses were performed. The hydroxyl substitution occurs as (OH)4 for (SiO4). The hydroxyl constituent in coffinite later proved to be nonessential in the formation of a stable synthetic mineral. Recent electron microprobe analysis of the submicroscopic crystals uncovered an abundance of calcium, yttrium, phosphorus, and minimal lead substitutions along with traces of other rare earth elements.

Quick Facts

Physical Properties

Color
Black
Hardness (Mohs)
5 - 6
Density
5.1 g/cm³

Chemical Properties

Chemical Formula
U(SiO4) · nH2O Also given as (U4+,Th)(SiO4)1-x(OH)4x
Elements
H, O, Si, U
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