Delafossite

A variety of Minerals

Delafossite specimen - rock identification

What is Delafossite?

Delafossite is a copper iron oxide mineral with formula CuFeO2 or CuFeO2. It is a member of the delafossite mineral group, which has the general formula ABO2, a group characterized by sheets of linearly coordinated A cations stacked between edge-shared octahedral layers (BO6). Delafossite, along with other minerals of the ABO2 group, is known for its wide range of electrical properties, its conductivity varying from insulating to metallic. Delafossite is usually a secondary mineral that crystallizes in association with oxidized copper and rarely occurs as a primary mineral.

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North ZoneCentral RidgeSouth Basin

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Key Characteristics

Characteristics of Delafossite

The color of delafossite is black, with a hardness of 5.5, and imperfect cleavage in the {1011} direction. Pabst calculated the density of delafossite to be 5.52. Contact twinning has been observed in the {0001} direction. The unit cell parameters were calculated to be a = 3.0351 Å, c = 17.166 Å, V = 136.94 Å. Delafossite is tabular to equidimensional in habit and has a black streak and a metallic luster. Delafossite has hexagonal symmetry that can have the space groups R3m or P63/mmc depending on the stacking of A cation layers. Delafossite compounds can have magnetic properties when magnetic ions are in the B cation position. Delafossite compounds also have properties dealing with electric conductivity such as insulation and/or metallic conduction. Delafossite compounds can exhibit p- or n-type conductivity based on their composition. Rhombohedral (3R), CuFeO2 properties: P-type semiconductor, bandgap 1.47 eV High light absorption coefficient of 7.5×10 cm near the band gap edge at 700 nm. High hole mobility of 34 cm v s even at doping levels as high as 1.8 × 10 cm. Good stability in aqueous environments. Hexagonal (2H), CuFeO2 properties: unknown as pure 2H CuFeO2 is very difficult to synthesize.

Quick Facts

Physical Properties

Color
Black, brown-white in reflected light
Hardness (Mohs)
5.5
Density
5.52 g/cm³
Streak
Black

Chemical Properties

Chemical Formula
CuFeO2
Elements
Cu, Fe, O
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