Triphylite
A variety of Minerals

What is Triphylite?
Triphylite is a lithium iron(II) phosphate mineral with the chemical formula LiFePO4. It is a member of the triphylite group and forms a complete solid solution series with the lithium manganese(II) phosphate, lithiophilite. Triphylite crystallizes in the orthorhombic crystal system. It rarely forms prismatic crystals and is more frequently found in hypidiomorphic rock. It is bluish- to greenish-gray in color, but upon alteration becomes brown to black.
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Key Characteristics
Characteristics of Triphylite
Triphylite is soluble in hydrochloric and sulfuric acid. Under a blowpipe, it melts to form a dark gray, magnetic ball. Over time, the mineral undergoes alteration by oxidation, increasing the oxidation state of iron from +2 to +3 and allowing the lithium to escape, forming heterosite, FePO4. Triphylite forms a complex solution series with lithiophilite, LiMnPO4, so that natural sources of triphylite usually contain manganese. The structures of members within this series are similar to olivine-type silicates.
Composition of Triphylite
Triphylite crystallizes in an orthorhombic crystal system. The lithium coordinates to six oxygen atoms in a distorted octahedron. Likewise, the iron centers are octahedrally coordinated. The structure contains isolated phosphate tetrahedra.
Quick Facts
Physical Properties
- Color
- Brown-green, light green-gray, may appear blue-gray, colourless to pale yellow in transmitted light
- Hardness (Mohs)
- 4
- Density
- 3.562 g/cm³
- Streak
- Colorless to grayish white
Chemical Properties
- Chemical Formula
- LiFe2+PO4
- Elements
- Fe, Li, O, P

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