Vanarsite
A variety of Minerals
What is Vanarsite?
Vanarsite, NaCa12(AsV3.5V8.5As6O51)2・78H2O, is a mineral that forms as very dark blue blades that are flattened on {100} and elongated on [010]. The crystals form in sub-parallel intergrowths in aggregates up to 5 mm long and are part of the cubic crystal system. The mineral is found in the Packrat mine in Colorado, USA in association with three mineral of similar composition, packratite, Ca11(AsV2V10As6O51)2・83H2O, morrisonite, Ca6(AsV2V10As6O51)2・78H2O, and gatewayite, Ca11(AsV3V9As6O51)・31H2O. Vanarsite has been determined to be part of the vanadate, arsenite, and arsenate groups. Analytical methods were used to determine its chemical composition, physical properties, and structure.
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Key Characteristics
Formation of Vanarsite
Vanarsite is a relatively rare mineral with only a small quantity of the mineral having been found. It was discovered in the main tunnel of the Packrat mine, Gateway district, Mesa County, Colorado, USA. Packrat mine is located in the northern part of the Uravan Mineral Belt where uranium and vanadium containing minerals often occur together in sandstone from the Salt Wash member of the Jurassic Morrison Formation. Vanarsite was found located with three other minerals that were discovered at the same time in the same locality, packratite, morrisonite, and gatewayite and is also associated with pharmacolite. The mineral forms from the oxidation of montroseite and corvusite minerals in moist environments. Oxidized and unoxidized phases are exposed from mining operations. Ambient temperatures and oxidizing conditions near the surface cause water to react with pyrite and an unknown arsenic bearing phase to form aqueous solutions with low pH. Various secondary vanadate phases form depending on Eh-pH conditions and other cations present.
Quick Facts
Physical Properties
- Color
- Very dark blue
- Hardness (Mohs)
- 2
- Density
- 2.46 g/cm³
- Streak
- Grayish blue
Chemical Properties
- Chemical Formula
- NaCa12(As3+V5+8.5V4+3.5As5+6O51)2·78H2O
- Elements
- As, Ca, H, Na, O, V

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