Widgiemoolthalite

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What is Widgiemoolthalite?

Widgiemoolthalite is a rare hydrated nickel(II) carbonate mineral with the chemical formula (Ni,Mg)5(CO3)4(OH)2·5H2O. Usually bluish-green in color, it is a brittle mineral formed during the weathering of nickel sulfide. Present on gaspéite surfaces, widgiemoolthalite has a Mohs scale hardness of 3.5 and an unknown though likely disordered crystal structure. Widgiemoolthalite was first discovered in 1992 in Widgiemooltha, Western Australia, which is to date its only known source. It was named the following year by the three researchers who first reported its existence, Ernest H. Nickel, Bruce W. Robinson, and William G. Mumme.

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North ZoneCentral RidgeSouth Basin

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Key Characteristics

Characteristics of Widgiemoolthalite

Hand specimens of widgiemoolthalite tend to be bluish-green though may also be grass-green in rare cases. Widgiemoolthalite is transparent in hand sample with a silky luster and a pale bluish-green streak. The mineral is brittle and breaks along its fiber contacts. Its observed specific gravity is 3.13(1) while its calculated specific gravity is 3.24, with a hardness of 3.5 on the Mohs scale. When viewed with polarized light under a petrographic microscope, widgiemoolthalite appears bluish-green and does not exhibit pleochroism. It is biaxial positive and has a high optic angle (or 2V). When measured perpendicular and parallel to its axis of anisotropy, its refractive indices are 1.630 and 1.640 respectively. This gives it a birefringence of 0.010.

Formation of Widgiemoolthalite

Widgiemoolthalite occurs as a secondary mineral. It is found overlaying nickel sulfide that has undergone weathering, often in hollow spaces on gaspéite surfaces, and often exhibiting fibrous and rarely massive crystal habits. Other minerals associated with widgiemoolthalite include annabergite, carrboydite, dolomite, glaukosphaerite, hydrohonessite, kambaldaite, magnesite, nepouite, nullaginite, olivenite, otwayite, paratacamite, pecoraite, reevesite, retgersite, and takovite. Two additional unnamed minerals were also reported as associated secondary minerals from the 132 North site, the only locality at which widgiemoolthalite has been found. The 132 North waste pile from which widgiemoolthalite was first recovered is no longer in existence, making it a rare mineral. In support of the designation of an Anthropocene epoch, the existence and provenance of widgiemoolthalite, along with 207 other mineral species, have been cited as evidence of uniquely human action upon global stratigraphy.

Composition of Widgiemoolthalite

Widgiemoolthalite is a nickel(II) carbonate that has undergone mineral hydration. Tests by Nickel, Robinson, and Mumme yielded the chemical formula (Ni,Mg)5.00(CO3)4.15-(OH)1.70·5.12H2O. The researchers observed that widgiemoolthalite is the nickel structural analog to the hydrated magnesium carbonate hydromagnesite and considering this relationship, determined that widgiemoolthalite's ideal makeup is Ni5(CO3)4(OH)2·4-5H2O though because it may contain either nickel or magnesium, widgiemoolthalite's makeup may also be written (Ni,Mg)5(CO3)4(OH)2·5H2O. By weight, the mineral is 49.58% oxygen, 34.41% nickel, 8.05% carbon, 6.11% magnesium, and 1.86% hydrogen. As of 2016, the exact crystal structure of widgiemoolthalite was not known though based on the patterns produced when the mineral was analyzed with X-ray crystallography, a high degree of structural disorder was suspected. Under an optical microscope, Nickel, Robinson, and Mumme reported difficulty discerning individual crystals as their lateral dimensions were too small. Crystals of widgiemoolthalite conform to a monoclinic system of symmetry, occupying space group P21/c. A unit cell of the mineral, the smallest divisible unit that possesses the same symmetry and properties, is packed with twice the atoms of its formula unit and has the dimensions a = 10.06(17), b = 8.75(5), and c = 8.32(4) Å. Each unit cell of widgiemoolthalite has a β value of 114.3(8)° and an approximate volume of 667.48 Å.

Quick Facts

Physical Properties

Color
Green, bluish-green
Hardness (Mohs)
3.5
Streak
Light green-blue

Chemical Properties

Chemical Formula
Ni5(CO3)4(OH)2 · 5H2O
Elements
C, H, Ni, O
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